Match each coordination compound in List-$I$ with an appropriate pair of characteristics from List-$II$ and select the correct answer using the code given below the lists. $\{en = H_2NCH_2CH_2NH_2\}$,atomic numbers:$\{Ti = 22; Cr = 24; Co = 27; Pt = 78\}$
List-$I$
List-$II$
$P$. $[Cr(NH_3)_4Cl_2]Cl$
$1$. Paramagnetic and exhibits ionisation isomerism
$Q$. $[Ti(H_2O)_5Cl](NO_3)_2$
$2$. Diamagnetic and exhibits cis-trans isomerism
$R$. $[Pt(en)(NH_3)Cl]NO_3$
$3$. Paramagnetic and exhibits cis-trans isomerism
$S$. $[Co(NH_3)_4(NO_3)_2]NO_3$
$4$. Diamagnetic and exhibits ionisation isomerism
| List-$I$ | List-$II$ |
|---|---|
| $P$. $[Cr(NH_3)_4Cl_2]Cl$ | $1$. Paramagnetic and exhibits ionisation isomerism |
| $Q$. $[Ti(H_2O)_5Cl](NO_3)_2$ | $2$. Diamagnetic and exhibits cis-trans isomerism |
| $R$. $[Pt(en)(NH_3)Cl]NO_3$ | $3$. Paramagnetic and exhibits cis-trans isomerism |
| $S$. $[Co(NH_3)_4(NO_3)_2]NO_3$ | $4$. Diamagnetic and exhibits ionisation isomerism |
- A$P-4, Q-2, R-3, S-1$
- B$P-3, Q-1, R-4, S-2$
- C$P-2, Q-1, R-3, S-4$
- D$P-1, Q-3, R-4, S-2$
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Similar Questions
Match List-$I$ with List-$II$ and select the correct option:
List-$I$ List-$II$ $(A). [Ag(CN)_2]^-$ $1. \text{Square planar, } 1.73 \, B.M.$ $(B). [Cu(CN)_4]^{3-}$ $2. \text{Linear, } 0 \, B.M.$ $(C). [Cu(CN)_6]^{4-}$ $3. \text{Octahedral, } 0 \, B.M.$ $(D). [Cu(NH_3)_4]^{2+}$ $4. \text{Tetrahedral, } 0 \, B.M.$ $(E). [Fe(CN)_6]^{4-}$ $5. \text{Octahedral, } 1.73 \, B.M.$
| List-$I$ | List-$II$ |
| $(A). [Ag(CN)_2]^-$ | $1. \text{Square planar, } 1.73 \, B.M.$ |
| $(B). [Cu(CN)_4]^{3-}$ | $2. \text{Linear, } 0 \, B.M.$ |
| $(C). [Cu(CN)_6]^{4-}$ | $3. \text{Octahedral, } 0 \, B.M.$ |
| $(D). [Cu(NH_3)_4]^{2+}$ | $4. \text{Tetrahedral, } 0 \, B.M.$ |
| $(E). [Fe(CN)_6]^{4-}$ | $5. \text{Octahedral, } 1.73 \, B.M.$ |
Difficult
View SolutionConsider the following complexes:
$(a) \ Na_2[Fe(CN)_5NO]$
$(b) \ [Fe(H_2O)_5NO]SO_4$
$(c) \ K_4[Fe(CN)_6]$
Which of the following statements is wrong?
$(a) \ Na_2[Fe(CN)_5NO]$
$(b) \ [Fe(H_2O)_5NO]SO_4$
$(c) \ K_4[Fe(CN)_6]$
Which of the following statements is wrong?
Medium
View SolutionThe colour of $CuCr_2O_7$ solution in water is green because
Medium
View SolutionGiven below are two statements:
Statement-$I$: Hybridisation, shape, and spin-only magnetic moment of $K_{3}[Co(CO_{3})_{3}]$ are $sp^{3}d^{2}$, octahedral, and $4.9 \ BM$ respectively.
Statement-$II$: Geometry, hybridisation, and spin-only magnetic moment values $(BM)$ of the ions $[Ni(CN)_{4}]^{2-}$, $[MnBr_{4}]^{2-}$, and $[CoF_{6}]^{3-}$ respectively are square planar, tetrahedral, octahedral; $dsp^{2}$, $sp^{3}$, $sp^{3}d^{2}$ and $0, 5.9, 4.9$.
Statement-$I$: Hybridisation, shape, and spin-only magnetic moment of $K_{3}[Co(CO_{3})_{3}]$ are $sp^{3}d^{2}$, octahedral, and $4.9 \ BM$ respectively.
Statement-$II$: Geometry, hybridisation, and spin-only magnetic moment values $(BM)$ of the ions $[Ni(CN)_{4}]^{2-}$, $[MnBr_{4}]^{2-}$, and $[CoF_{6}]^{3-}$ respectively are square planar, tetrahedral, octahedral; $dsp^{2}$, $sp^{3}$, $sp^{3}d^{2}$ and $0, 5.9, 4.9$.
DifficultJEE MAIN 2026
View Solution$A$ mixture $X$ of $0.02 \, mol$ of $[Co(NH_3)_5SO_4]Br$ and $0.02 \, mol$ of $[Co(NH_3)_5Br]SO_4$ was prepared in $2 \, L$ of solution:
$1 \, L$ of mixture $X +$ excess of $AgNO_3 \to Y$
$1 \, L$ of mixture $X +$ excess of $BaCl_2 \to Z$
Number of moles of $Y$ and $Z$ respectively are
$1 \, L$ of mixture $X +$ excess of $AgNO_3 \to Y$
$1 \, L$ of mixture $X +$ excess of $BaCl_2 \to Z$
Number of moles of $Y$ and $Z$ respectively are
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