Match List-$I$ with List-$II$ :
List-$I$ (Chemical Reaction) List-$II$ (Reagent used)
$(a)$ $CH_{3}COOCH_{2}CH_{3} \rightarrow CH_{3}CH_{2}OH$ $(i)$ $CH_{3}MgBr / H_{3}O^{+}$ ($1$ equivalent)
$(b)$ $CH_{3}COOCH_{3} \rightarrow CH_{3}CHO$ $(ii)$ $H_{2}SO_{4} / H_{2}O$
$(c)$ $CH_{3}C \equiv N \rightarrow CH_{3}CHO$ $(iii)$ $DIBAL-H / H_{2}O$
$(d)$ $CH_{3}C \equiv N \rightarrow CH_{3}COCH_{3}$ $(iv)$ $SnCl_{2}, HCl / H_{2}O$

Choose the most appropriate match :

  • A
    $a-ii, b-iv, c-iii, d-i$
  • B
    $a-iv, b-ii, c-iii, d-i$
  • C
    $a-ii, b-iii, c-iv, d-i$
  • D
    $a-iii, b-ii, c-i, d-iv$

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Similar Questions

Assertion : The $pK_a$ of acetic acid is lower than that of phenol.
Reason : Phenoxide ion is more resonance stabilised.

In Column-$I$ formula,in Column-$II$ general name and in Column-$III$ $IUPAC$ name are given. Match the items in Column-$I$ with the appropriate items in Column-$II$ and Column-$III$.
Column-$I$ (Formula) Column-$II$ (General Name) and Column-$III$ ($IUPAC$ Name)
$(A)$ $HCOOH$ $(i)$ Succinic acid,$(x)$ Methanoic acid
$(B)$ $CH_3CH_2CH_2COOH$ $(ii)$ Oxalic acid,$(y)$ Ethanedioic acid
$(C)$ $(COOH)_2$ $(iii)$ Formic acid,$(m)$ Butanedioic acid
$(D)$ $(CH_2)_2(COOH)_2$ $(iv)$ Butyric acid,$(n)$ Butanoic acid

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Which $\beta$-keto acid shown will not undergo decarboxylation?

Match Column-$I$ with Column-$II$ :
| Column-$I$ | Column-$II$ |
| :--- | :--- |
| $(A)$ Cyclopentanone + $2,4-$$DNP$ $\xrightarrow{\text{mild } H^+}$ Cyclopentanone$-2,4-$$DNP$ derivative | $(P)$ Electrophilic substitution |
| $(B)$ $4-$phenyl$-2-$methylbutan$-2-$ol $\xrightarrow{\text{Conc. } H_2SO_4}$ $1,1-$dimethyl$-1,2,3,4-$tetrahydronaphthalene | $(Q)$ Nucleophilic substitution |
| $(C)$ $4-$chlorocyclohexanethiol $\xrightarrow{\text{Base}}$ $7-$thiabicyclo[$2.2$.$1$]heptane | $(R)$ Nucleophilic addition |

The products $A$ and $B$ in the following reaction sequence are:

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