Match the following:

List-$I$	List-$II$
$A$. $ABCABC...$ layers	$I$. $F$-centres
$B$. Thermodynamics defects	$II$. $X$-ray diffraction
$C$. $Farbenzenter$	$III$. Vacancy defects
$D$. $Debye-Scherrer$ method	$IV$. Semiconductors
	$V$. Silver

The setting of cement is an ....... process.

Which of the following statements is correct?

Atoms of metals $x$,$y$,and $z$ form face-centred cubic $(fcc)$ unit cell of edge length $L_x$,body-centred cubic $(bcc)$ unit cell of edge length $L_y$,and simple cubic unit cell of edge length $L_z$,respectively. If $r_z = \frac{\sqrt{3}}{2} r_y$; $r_y = \frac{8}{\sqrt{3}} r_x$; $M_z = \frac{3}{2} M_y$ and $M_z = 3 M_x$,then the correct statement$(s)$ is (are) [Given: $M_x$,$M_y$,and $M_z$ are molar masses of metals $x$,$y$,and $z$,respectively. $r_x$,$r_y$,and $r_z$ are atomic radii of metals $x$,$y$,and $z$,respectively.]
$(A)$ Packing efficiency of unit cell of $x >$ Packing efficiency of unit cell of $y >$ Packing efficiency of unit cell of $z$
$(B)$ $L_y > L_z$
$(C)$ $L_x > L_y$
$(D)$ Density of $x >$ Density of $y$

$A$ mixture of $KCl$ and $KF$ is added to sodium chloride.

Calculate the number of atoms present in $1.625 \text{ g}$ of a metal that forms a $bcc$ unit cell structure. Given: $[\rho \times a^3 = 3.25 \times 10^{-22} \text{ g}]$.