Which of the following statements is correct?

Calculate the number of atoms present in $1.58 \ g$ of a metal that forms a $bcc$ structure,given that $\varrho \times a^3 = 1.58 \times 10^{-22} \ g$.

Calculate the volume of the unit cell of an element with a density of $7.2 \ g \ cm^{-3}$ that forms a $bcc$ structure. ($288 \ g$ of this element contains $3.35 \times 10^{24}$ atoms).

Give the correct order of initials $T$ (true) or $F$ (false) for the following statements:
$I.$ In an anti-fluorite structure,anions form $FCC$ lattice and cations occupy all tetrahedral voids.
$II.$ If the radius of cations and anions are $0.2 \ \mathring{A}$ and $0.95 \ \mathring{A}$,then the coordination number of the cation in the crystal is $4$.
$III.$ An atom/ion is transferred from a lattice site to an interstitial position in a Frenkel defect.
$IV.$ The density of a crystal always increases due to a substitutional impurity defect.

Which one of the following statements is correct?

What is the percent by mass of titanium in rutile,a mineral that contains titanium and oxygen,if the structure can be described as a closest-packed array of oxide ions,with titanium in one half of the octahedral holes? What is the oxidation number of titanium? $(Ti = 48, O = 16)$