Niobium crystallises in a body-centred cubic $(bcc)$ structure. If the density is $8.55 \, g \, cm^{-3}$,calculate the atomic radius of niobium using its atomic mass $93 \, u$.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) Given: Density $(d)$ = $8.55 \, g \, cm^{-3}$,Atomic mass $(M)$ = $93 \, g \, mol^{-1}$,$z$ (for $bcc$) = $2$,Avogadro's number $(N_{A})$ = $6.022 \times 10^{23} \, mol^{-1}$.
Using the formula for density: $d = \frac{z \cdot M}{a^{3} \cdot N_{A}}$.
Rearranging for edge length $(a)$: $a^{3} = \frac{z \cdot M}{d \cdot N_{A}} = \frac{2 \times 93}{8.55 \times 6.022 \times 10^{23}} \approx 3.612 \times 10^{-23} \, cm^{3}$.
Taking the cube root: $a \approx 3.306 \times 10^{-8} \, cm$.
For a $bcc$ structure,the relation between radius $(r)$ and edge length $(a)$ is: $r = \frac{\sqrt{3}}{4} \cdot a$.
Substituting the value of $a$: $r = \frac{1.732}{4} \times 3.306 \times 10^{-8} \, cm \approx 1.432 \times 10^{-8} \, cm$ or $0.1432 \, nm$.

Explore More

Similar Questions

$A$ face-centered cubic $(FCC)$ solid of an element (atomic mass $60$) has a cubic edge length of $4 \times 10^{-8} \, cm$. If Avogadro's number is $6 \times 10^{23} \, mol^{-1}$,then the density of the solid is:

Difficult
View Solution

$KCl$ has the same structure as $NaCl$. If ${r_{Na^+}}/{r_{Cl^-}} = 0.55$ and ${r_{Na^+}}/{r_{K^+}} = 0.74$,then the ratio of the edge lengths of $KCl$ and $NaCl$ is:

Sodium crystallizes in $bcc$ structure with radius $1.86 \times 10^{-8} \text{ cm}$. What is the edge length of unit cell of sodium?

Gold (atomic radius $= 0.144 \, nm$) crystallises in a face-centred unit cell. What is the length of a side of the cell?

Copper (atomic mass $= 63.5$) crystallises in a $fcc$ lattice and has density $8.93 \, g \, cm^{-3}$. The radius of copper atom is closest to $.... \, pm$.

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo