Of all the three common mineral acids,only sulphuric acid is found to be suitable for making the solution acidic in redox titrations involving $KMnO_4$ because:

$KMnO_4$ is titrated with ferrous ammonium sulphate hexahydrate in the presence of dilute $H_2SO_4$. The number of water molecules produced for $2$ molecules of $KMnO_4$ is $..........$.

Given below are two statements: One is labelled as Assertion $A$ and the other is labelled as Reason $R$.
Assertion $A$: Permanganate titrations are not performed in the presence of hydrochloric acid.
Reason $R$: Chlorine is formed as a consequence of the oxidation of hydrochloric acid.
In the light of the above statements,choose the correct answer from the options given below.

The ammonia evolved from the treatment of $0.30 \, g$ of an organic compound for the estimation of nitrogen was passed in $100 \, mL$ of $0.1 \, M$ sulphuric acid. The excess of acid required $20 \, mL$ of $0.5 \, M$ sodium hydroxide solution for complete neutralization. The organic compound is:

$K_2Cr_2O_7$ is preferred to $Na_2Cr_2O_7$ for use in volumetric analysis as a primary standard because

$500 \ mL$ of $1.2 \ M$ $KI$ solution is mixed with $500 \ mL$ of $0.2 \ M$ $KMnO_4$ solution in basic medium. The liberated iodine was titrated with standard $0.1 \ M$ $Na_2S_2O_3$ solution in the presence of starch indicator till the blue color disappeared. The volume (in $L$) of $Na_2S_2O_3$ consumed is . . . . . . . (Nearest integer)