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Question

(C) The reaction of phenol with acetyl chloride $(CH_3COCl)$ in the presence of a base forms phenyl acetate as product $(P)$.This is an esterification

Vedclass · Accepted Answer

$p$-Hydroxyacetophenone

Vedclass · Answer

(C) The reaction of phenol with acetyl chloride $(CH_3COCl)$ in the presence of a base forms phenyl acetate as product $(P)$.This is an esterification reaction.When phenyl acetate $(P)$ is heated with anhydrous $AlCl_3$,it undergoes Fries rearrangement to form a mixture of $o$-hydroxyacetophenone and $p$-hydroxyacetophenone.$p$-Hydroxyacetophenone is the major product $(Q)$ at higher temperatures.Therefore,the correct option is $(C)$.

Product $(Q)$ in this reaction is

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