Splitting of signals in $NMR$ spectroscopy is caused by

Which of the following statements regarding the chemical properties of acetophenone is incorrect?
$I.$ It is reduced to methyl phenyl carbinol by sodium and ethanol.
$II.$ It is oxidized to benzoic acid with acidic $KMnO_4$.
$III.$ It does not undergo electrophilic substitution reactions (like nitration at the $m$-position).
$IV.$ It does not give the iodoform test with iodine and alkali.

In the following table,Column-$I$ shows the structure of a compound,Column-$II$ shows its $IUPAC$ name,and Column-$III$ shows its common name. Match the $IUPAC$ name and common name for each structure given in Column-$I$.
| Column-$I$ (Structure) | Column-$II$ ($IUPAC$ name) | Column-$III$ (Common name) |
| :--- | :--- | :--- |
| $(A)$ $C_6H_4(CHO)_2$ (ortho) | $(i)$ Benzophenone | $(p)$ Acrolein |
| $(B)$ $(CH_3)_2C=CHCOCH_3$ | $(ii)$ Benzene$-1,2-$dicarbaldehyde | $(q)$ Diphenyl ketone |
| $(C)$ $CH_2=CH-CHO$ | $(iii)$ Prop$-2-$enal | $(r)$ Phthaldehyde |
| $(D)$ $(C_6H_5)_2CO$ | $(iv)$ $4-$methylpent$-3-$en$-2-$one | $(s)$ Mesityl oxide |

What are $X$ and $Y$ in the following reaction sequence?
$Toluene$ $\xrightarrow{X} Benzaldehyde$ $\xrightarrow{HNO_3 + H_2SO_4, 273-283 \ K} Y$

Match the reactions in Column $I$ with appropriate options in Column $II$.

Column $I$	Column $II$
$A$. $Ph-N_2Cl + Ph-OH \xrightarrow{NaOH/H_2O, 0^{\circ}C} Ph-N=N-Ph-OH$	$p$. Racemic mixture
$B$. $Pinacol \xrightarrow{H_2SO_4} Pinacolone$	$q$. Addition reaction
$C$. $Ph-CO-CH_3 \xrightarrow{1. LiAlH_4, 2. H_3O^+} Ph-CH(OH)-CH_3$	$r$. Substitution reaction
$D$. $4-chlorocyclohexanethiol \xrightarrow{Base} Thiacycloheptane$	$s$. Coupling reaction
	$t$. Carbocation intermediate

Explain the preparation of hydrocarbon compounds by the Clemmensen reduction reaction.