Standard entropies of $X_2$,$Y_2$ and $XY_3$ are $60$,$40$ and $50 \ J \ K^{-1} \ mol^{-1}$ respectively. For the reaction $\frac{1}{2} X_2 + \frac{3}{2} Y_2 \rightarrow XY_3$,the enthalpy change is $\Delta H = -30 \ kJ \ mol^{-1}$. At what temperature will the reaction be at equilibrium (in $K$)?

For the complete combustion of methanol
$CH_3OH_{(l)} + \frac{3}{2} O_{2(g)} \rightarrow CO_{2(g)} + 2H_2O_{(l)}$
the amount of heat produced as measured by a bomb calorimeter is $726 \ kJ \ mol^{-1}$ at $27^{\circ}C$. The enthalpy of combustion for the reaction is $-x \ kJ \ mol^{-1}$,where $x$ is $.....$ (Nearest integer).
(Given: $R = 8.3 \ J \ K^{-1} \ mol^{-1}$)

An ideal gas undergoes a reversible isothermal expansion from state $I$ to state $II$ followed by a reversible adiabatic expansion from state $II$ to state $III$. The correct plot$(s)$ representing the changes from state $I$ to state $III$ is(are)
($p$ : pressure,$V$ : volume,$T$ : temperature,$H$ : enthalpy,$S$ : entropy)

Which of the following relations is correct?

At $298 \ K$,$\Delta_r U^{\ominus}$ and $\Delta_r S^{\ominus}$ for the following reaction are $-10.5 \ kJ$ and $+44.1 \ J \ K^{-1} \ mol^{-1}$ respectively. The reaction is: $2 \ X_{(g)} + Y_{(g)} \longrightarrow 2 \ Z_{(g)}$. What is $\Delta_r G^{\ominus}$ (in $kJ$) for this reaction? $(R = 8.314 \ J \ K^{-1} \ mol^{-1})$

One mole of an ideal monoatomic gas is heated in a process $PV^{5/2} = \text{constant}$. The amount of heat absorbed in the process for a $36 \ ^\circ C$ rise in temperature is (in $cal$):