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Which of the following statements is incorrect for a buffer solution?

Assertion : Buffer system of carbonic acid and sodium bicarbonate is used for the precipitation of hydroxides of third group elements.
Reason : It maintains the $pH$ to a constant value,about $7.4.$

Class $XII$ students were asked to prepare one litre of buffer solution of $pH$ $8.26$ by their chemistry teacher. The amount of ammonium chloride to be dissolved by the student in $0.2 \, M$ ammonia solution to make one litre of the buffer is $..... \, g$ (Given $pK_b(NH_3)=4.74$; Molar mass of $NH_3=17 \, g \, mol^{-1}$; Molar mass of $NH_4Cl =53.5 \, g \, mol^{-1}$)

$A$ buffer solution can be prepared from a mixture of

The $K_a$ of $CH_3COOH$ is $1.8 \times 10^{-5}$. How many grams of $CH_3COONa$ are required in $0.1 \ M \ CH_3COOH$ to form a solution having $pH = 4.0$? (Molecular mass of $CH_3COONa = 82 \ g \ mol^{-1}$)

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