The formula of the product formed, when sodium thiosulphate solution is added to silver bromide is

  • A
    $Ag_2S_2O_3$
  • B
    $Ag_2S$
  • C
    $Na_3[Ag(S_2O_3)_2]$
  • D
    $Ag_3[Na(S_2O_3)_2]$

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The stepwise stability constants of a complex are given below. What is its overall reaction stability constant $\beta_4$ ?
$M + L \rightleftharpoons ML ; K_1 = 1.0 \times 10^4$
$ML + L \rightleftharpoons ML_2 ; K_2 = 1.0 \times 10^3$
$ML_2 + L \rightleftharpoons ML_3 ; K_3 = 1.0 \times 10^3$
$ML_3 + L \rightleftharpoons ML_4 ; K_4 = 1.0 \times 10^2$
(Overall reaction : $M + 4L \rightleftharpoons ML_4$)

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The $\pi-$acid ligand which uses its $d-$orbital during synergic bonding in its complex compound is:

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