The major product $Z$ formed in the following sequence of reactions is:

  • A
    $C_2H_5-N=N-OH$
  • B
    $C_2H_5OH$
  • C
    $C_2H_5NO_2$
  • D
    $C_2H_5NH_2$

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$(i)$ Write structures of different isomeric amines corresponding to the molecular formula,$C_{4}H_{11}N$. $(ii)$ Write $IUPAC$ names of all the isomers. $(iii)$ What type of isomerism is exhibited by different pairs of amines?

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The final product $A$, formed in the following multistep reaction sequence is:

Match the Compounds (List-$I$) with the appropriate Catalyst/Reagents (List-$II$) for their reduction or conversion into corresponding amines.
List-$I$ (Compounds) List-$II$ (Catalyst/Reagents)
$A$. $R-CONH_2$ $I$. $NaOH$ (aqueous)
$B$. $C_6H_5NO_2$ $II$. $H_2 / Ni$
$C$. $R-C \equiv N$ $III$. $LiAlH_4, H_2O$
$D$. $N$-alkylphthalimide $IV$. $Sn,HCl$

Choose the correct answer from the options given below:

Match each of the compounds in Column $I$ with its characteristic reaction$(s)$ in Column $II$.
Column $I$ Column $II$
$A$. $CH_3CH_2CH_2CN$ $p$. Reduction with $Pd-C/H_2$
$B$. $CH_3CH_2OCOCH_3$ $q$. Reduction with $SnCl_2/HCl$
$C$. $CH_3-CH=CH-CH_2OH$ $r$. Development of foul smell on treatment with chloroform and alcoholic $KOH$
$D$. $CH_3CH_2CH_2CH_2NH_2$ $s$. Reduction with diisobutylaluminium hydride $(DIBAL-H)$
$t$. Alkaline hydrolysis

Identify $C$ in the following reaction sequence:
$Cyclohexanone$ $\xrightarrow[\text{Alkaline medium}]{HCN} A$ $\xrightarrow{LiAlH_4} B$ $\xrightarrow{NaNO_2/HCl} C$

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