$(i)$ Write structures of different isomeric amines corresponding to the molecular formula,$C_{4}H_{11}N$. $(ii)$ Write $IUPAC$ names of all the isomers. $(iii)$ What type of isomerism is exhibited by different pairs of amines?

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(A) $(i), (ii)$ The structures and their $IUPAC$ names of different isomeric amines corresponding to the molecular formula,$C_{4}H_{11}N$ are:
$(a)$ $CH_{3}CH_{2}CH_{2}CH_{2}NH_{2}$: $\text{Butan-1-amine } (1^{\circ})$
$(b)$ $CH_{3}CH_{2}CH(NH_{2})CH_{3}$: $\text{Butan-2-amine } (1^{\circ})$
$(c)$ $(CH_{3})_{2}CHCH_{2}NH_{2}$: $\text{2-Methylpropan-1-amine } (1^{\circ})$
$(d)$ $(CH_{3})_{3}CNH_{2}$: $\text{2-Methylpropan-2-amine } (1^{\circ})$
$(e)$ $CH_{3}CH_{2}CH_{2}NHCH_{3}$: $\text{N-Methylpropan-1-amine } (2^{\circ})$
$(f)$ $CH_{3}CH_{2}NHCH_{2}CH_{3}$: $\text{N-Ethylethanamine } (2^{\circ})$
$(g)$ $CH_{3}CH(CH_{3})NHCH_{3}$: $\text{N-Methylpropan-2-amine } (2^{\circ})$
$(h)$ $CH_{3}CH_{2}N(CH_{3})_{2}$: $\text{N,N-Dimethylethanamine } (3^{\circ})$
$(iii)$ The pairs $(a)$ and $(b)$,and $(e)$ and $(g)$ exhibit position isomerism.
The pairs $(a)$ and $(c)$,$(a)$ and $(d)$,$(b)$ and $(c)$,and $(b)$ and $(d)$ exhibit chain isomerism.
The pairs $(e)$ and $(f)$,and $(f)$ and $(g)$ exhibit metamerism.
Primary,secondary,and tertiary amines exhibit functional isomerism with each other.

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Similar Questions

In which of the following reactions is a tertiary amine formed?

Given below are two statements:
Statement-$I$ : Oxidation of $p$-nitrotoluene with acidic $KMnO_4$ gives an acid that is stronger than benzoic acid.
Statement-$II$ : Reduction of $p$-nitrotoluene with $Sn/HCl$ followed by neutralization gives an amine that is more basic than aniline.
In light of the above statements, choose the most appropriate answer from the options given below.

Match List-$I$ with List-$II$:
List-$I$ List-$II$
$A$. Benzenesulphonyl chloride $I$. Test for primary amines
$B$. Hoffmann bromamide reaction $II$. Anti Saytzeff
$C$. Carbylamine reaction $III$. Hinsberg reagent
$D$. Hoffmann orientation $IV$. Known reaction of isocyanates

Choose the correct answer from the options given below.

Which of the following species would not be involved in the Hoffmann rearrangement shown below?

$E \xleftarrow{KOH/Br_2} D \xleftarrow{H_2O_2/OH^{-} \atop (Partial \ Hydrolysis)} C \xleftarrow{NaCN} C_2H_5-Cl$ $\xrightarrow{AgCN} A$ $\xrightarrow{LiAlH_4} B$
What is the relationship between $B$ and $E$?

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