The mechanism of the reaction,$2NO_{(g)} + 2H_{2(g)} \to N_{2(g)} + 2H_2O_{(g)}$ is:
Step $1$: $2NO_{(g)} + H_{2(g)} \xrightarrow{\text{slow}} N_2 + H_2O_2$
Step $2$: $H_2O_2 + H_2 \xrightarrow{\text{fast}} 2H_2O$
Then the correct statement is:

  • A
    Rate $= k [NO]^2 [H_2]$
  • B
    Rate $= k [H_2O_2] [H_2]$
  • C
    On doubling the concentration of $H_2$,keeping the concentration of $NO$ constant,the rate will become double
  • D
    If the initial concentration of $H_2$ and $NO$ is $C_0$ and after time $t$ the concentration of $N_2$ is $x$,then Rate $= k (C_0 - 2x)^2$

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Similar Questions

For the reaction $2NO + Cl_2 \rightarrow 2NOCl$,the following mechanism is proposed. What will be the rate law for the reaction? $NO + Cl_2 \rightleftharpoons NOCl_2$ (fast); $NOCl_2 + NO \rightarrow 2NOCl$ (slow)

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What is the molecularity and order of the following reaction if the rate law is $\text{rate} = k[O_3][O]$ respectively?
$O_{3(g)} + O_{(g)} \longrightarrow 2O_{2(g)}$

For the reaction:
$2NO_{2(g)} + O_{3(g)} \to N_2O_{5(g)} + O_{2(g)}$
The rate law is $R = K[NO_2]^1 [O_3]^1$.
Which of these possible reaction mechanisms is consistent with the rate law?
Mechanism $I$:
$NO_{2(g)} + O_{3(g)} \to NO_{3(g)} + O_{2(g)}$ (slow)
$NO_{3(g)} + NO_{2(g)} \to N_2O_{5(g)}$ (fast)
Mechanism $II$:
$O_{3(g)} \rightleftharpoons O_{2(g)} + [O]$ (fast)
$NO_{2(g)} + [O] \to NO_3$ (slow)
$NO_{3(g)} + NO_{2(g)} \to N_2O_5$ (fast)

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Ozone decomposes into oxygen as follows:
$O_3 \rightleftharpoons O_2 + [O]$
$O_3 + [O] \to 2O_2$ (slow)
Determine the order of the reaction $2O_3 \to 3O_2$.

The conversion of molecules $X$ to $Y$ follows second order kinetics. If the concentration of $X$ is increased to three times,how will it affect the rate of formation of $Y$?

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