The molar enthalpy change for $H_2O_{(l)} \rightleftharpoons H_2O_{(g)}$ at $373 \ K$ and $1 \ atm$ is $41 \ kJ \ mol^{-1}$. Assuming ideal behavior,the internal energy change for vaporization of $1 \ mol$ of water at $373 \ K$ and $1 \ atm$ in $kJ \ mol^{-1}$ is:

Which of the following $p-V$ curves represents the maximum work done?

Match the following:

$(a)$ Entropy of vaporization	$(1)$ Decreases
$(b)$ $K$ for spontaneous process	$(2)$ Always has a $(+)$ value
$(c)$ Crystalline solid state	$(3)$ Has minimum entropy
$(d)$ $\Delta U$ for adiabatic expansion of an ideal gas	$(4)$ $\frac{\Delta H_{vap}}{T_b}$

One mole of $CH_3OH$ is vaporized at $338 \ K$ and $1.5 \ atm$ pressure. If the enthalpy of vaporization of $CH_3OH$ is $35.57 \ kJ/mol$,calculate the value of $\Delta U$ for the process in $kJ$. (in $.76$)

The ratio of heats liberated at $298 \ K$ from the combustion of one $kg$ of coke and by burning water gas obtained from $1 \ kg$ of coke is. (Assume coke to be $100 \%$ carbon.) (Given enthalpies of combustion of $CO_{2}, CO$ and $H_{2}$ as $393.5 \ kJ/mol, 283.5 \ kJ/mol, 285.5 \ kJ/mol$ respectively all at $298 \ K$.) (in $: 1$)

Which of the following relations is not correct?