The reaction of aniline with chloroform under | vedclass

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Question

(B) Aniline is a primary amine (contains $-NH_{2}$ group). When it is treated with chloroform $(CHCl_{3})$ under alkaline conditions (using $KOH$), it

Vedclass · Accepted Answer

phenylisonitrile

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(B) Aniline is a primary amine (contains $-NH_{2}$ group). When it is treated with chloroform $(CHCl_{3})$ under alkaline conditions (using $KOH$), it results in the formation of a bad-smelling compound known as phenyl isonitrile (or phenyl carbylamine). The chemical reaction is: $C_{6}H_{5}NH_{2} + CHCl_{3} + 3KOH(alc.) \rightarrow C_{6}H_{5}NC + 3KCl + 3H_{2}O$. This reaction is known as the carbylamine reaction.

The reaction of aniline with chloroform under alkaline conditions leads to the formation of

Similar Questions

The major product of the reaction shown below is:

$H_3CCONH_2 + Br_2 + 4NaOH \longrightarrow Y + Na_2CO_3 + 2NaBr + 2H_2O$
What is $Y$ in the above reaction?

Product $(B)$ of this reaction is

The relative basic strength of the compounds is correctly shown in the option.

Consider the following:
Statement-$I$: In the nitration of aniline,a significant amount of $m$-nitroaniline is formed.
Statement-$II$: In the presence of a strongly acidic medium,aniline is protonated to form the anilinium ion,which is meta-directing.

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