The reagent which can perform the conversion $CH_{3}COOH \longrightarrow CH_{3}CH_{2}OH$ is

  • A
    $LiAlH_{4} / \text{ether}$
  • B
    $H_{2}, Pt$
  • C
    $NaBH_{4}$
  • D
    $Na \text{ and } C_{2}H_{5}OH$

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Give the reactions of benzoic acid $(C_6H_5COOH)$ with the following:
$(i)$ Sodium metal
$(ii)$ Solution of sodium hydroxide $(NaOH)$
$(iii)$ Solution of sodium bicarbonate $(NaHCO_3)$
$(iv)$ $P_2O_5$ or conc. $H_2SO_4$ $+$ heat
$(v)$ $PCl_5$
$(vi)$ $PCl_3$
$(vii)$ $SOCl_2$
$(viii)$ $NH_3$ $+$ high temperature
$(ix)$ $LiAlH_4$ / ether or $B_2H_6$
$(x)$ Sodalime $(NaOH + CaO)$ $+$ heat
$(xi)$ Conc. $HNO_3$ $+$ conc. $H_2SO_4$ $+$ heat
$(xii)$ $Br_2 + FeBr_3$
$(xiii)$ Oleum $(H_2SO_4 + SO_3)$ $+$ heat

Which of the following is most acidic?

Which one of the following compounds does not give benzoic acid when treated with alkaline $KMnO_4$?

Treatment of benzoic acid with $Cl_2/FeCl_3$ will give

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