The specific rate constant of a $1^{st}$ order reaction depends on the

  • A
    Concentration of the reactants
  • B
    Concentration of the products
  • C
    Time of reaction
  • D
    Temperature of reaction

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Fill in the blank :
$1.$ In collision theory the molecules are hard .........
$2.$ In a reality the molecules are hard ..........
$3.$ Collision take place with .......... species.

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If the rate constants of a reaction at $500 \ K$ and $700 \ K$ are $0.002 \ s^{-1}$ and $0.06 \ s^{-1}$,respectively,the value of activation energy is $(R=8.314 \ J \ mol^{-1} \ K^{-1}, \log 3=0.477)$.

What will be the effect of temperature on the rate constant?

Given below are two statements: one is labelled as Assertion $A$ and the other is labelled as Reason $R$.
Assertion $A$: $A$ reaction can have zero activation energy.
Reason $R$: The minimum extra amount of energy absorbed by reactant molecules so that their energy becomes equal to threshold value,is called activation energy.
In the light of the above statements,choose the correct answer from the options given below:

At $527 \, ^{\circ}C$ temperature,the activation energy is $54.7 \, kJ/mol$. The value of the Arrhenius factor is $4 \times 10^{10}$. The rate constant will be:

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