The vapour pressure of a non-ideal two-component solution is given below. Identify the correct $B.P.-x$ curve for the same mixture.

Select the correct statement.

$P$ and $Q$ combine to form two compounds $PQ_2$ and $PQ_3$. If $1 \ g$ of $PQ_2$ is dissolved in $51 \ g$ of benzene, the depression of freezing point is $0.8^{\circ} C$. If $1 \ g$ of $PQ_3$ is dissolved in $51 \ g$ of benzene, the depression of freezing point is $0.625^{\circ} C$. Given $K_f$ of benzene $= 5.1 \ K \ kg \ mol^{-1}$, calculate the atomic masses of $P$ and $Q$.

$A$ non-volatile solute is dissolved in water. The $\Delta T_b$ of the resultant solution is $0.052 \ K$. What is the freezing point of the solution (in $K$)?
($K_b$ of water $= 0.52 \ K \ kg \ mol^{-1}$; $K_f$ of water $= 1.86 \ K \ kg \ mol^{-1}$,Freezing point of water $= 273 \ K$)

Which of the following has the lowest freezing point?

At $35^{\circ} C$,the vapour pressure of $CS_{2}$ is $512 \; mm \; Hg$ and that of acetone is $344 \; mm \; Hg$. $A$ solution of $CS_{2}$ in acetone has a total vapour pressure of $600 \; mm \; Hg$. The false statement amongst the following is