When $1.0 \ g$ of solid oxalic acid $(H_2C_2O_4)$ is burned in a bomb calorimeter whose heat capacity is $8.75 \ kJ/K$,the temperature increases by $0.312 \ K$. The enthalpy of combustion of oxalic acid at $27 \ ^oC$ is

From the following data,the enthalpy of dilution of $KCl$ will be ............ $kJ$.
$KCl_{(s)} + 20H_2O \to KCl(20H_2O); \Delta H = + 15.90 \ kJ$
$KCl_{(s)} + 200H_2O \to KCl(200H_2O); \Delta H = + 18.58 \ kJ$

In a constant volume calorimeter,$3.5 \ g$ of a gas with molecular weight $28$ was burnt in excess oxygen at $298.0 \ K$. The temperature of the calorimeter was found to increase from $298.0 \ K$ to $298.45 \ K$ due to the combustion process. Given that the heat capacity of the calorimeter is $2.5 \ kJ \ K^{-1}$,the numerical value for the enthalpy of combustion of the gas in $kJ \ mol^{-1}$ is

In an adiabatic process,the work involved during expansion or compression of an ideal gas is given by

Identify the correct statements from the following.
$I$. At $0 \ K$,the entropy of pure crystalline materials approaches zero.
$II$. Entropy for the process,$H_2O_{(l)} \longrightarrow H_2O_{(g)}$ decreases.
$III$. Gibbs' energy is a state function.

Calculate the enthalpy change when $50 \ mL$ of $0.01 \ M$ $Ca(OH)_2$ reacts with $25 \ mL$ of $0.01 \ M$ $HCl$. Given that $\Delta H^o$ for neutralization of a strong acid and a strong base is $-13.7 \ kcal \ mol^{-1}$. (Note: The provided value in the prompt $140 \ kcal \ mol^{-1}$ is physically incorrect for neutralization; using standard value $-13.7 \ kcal \ mol^{-1}$ for calculation). (in $kcal$)