Which of the following compounds cannot form iodoform?

  • A
    Ethyl methyl ketone
  • B
    Isopropyl alcohol
  • C
    $3-\text{Methyl}-2-\text{butanone}$
  • D
    Isobutyl alcohol

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The product $(A)$ of the reaction is:

The product $(B)$ in the given reaction is:

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$A$ carbonyl compound $P$,which gives a positive iodoform test,undergoes reaction with $MeMgBr$ followed by dehydration to give an olefin $Q$. Ozonolysis of $Q$ leads to a dicarbonyl compound $R$,which undergoes intramolecular aldol reaction to give predominantly $S$.
$P$ $\xrightarrow[\substack{2. H^{+}, H_2 O \\ 3. H_2 SO_4, \Delta}]{1. MeMgBr} Q$ $\xrightarrow[2. Zn, H_2 O]{1. O_3} R$ $\xrightarrow[2. \Delta]{1. OH^{-}} S$
$1.$ The structure of the carbonyl compound $P$ is
$2.$ The structures of the products $Q$ and $R$,respectively,are
$3.$ The structure of the product $S$ is
Give the answer for questions $1, 2$ and $3.$

Which of the following compounds does not give a positive Fehling's test?

$CH_3-CH(OH)-CH_2-CHO$
$3HCHO + A \xrightarrow[40^o C]{Na_2CO_3} (B) (82\%)$
Product $(B)$ of the above reaction is

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