Which of the following is most soluble in water?

  • A
    $AgCl$
  • B
    $PbCl_2$
  • C
    $LiCl$
  • D
    $NaCl$

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In qualitative analysis,the metals of group $I$ can be separated from other ions by precipitating them as chloride salts. $A$ solution initially contains $Ag^{+}$ and $Pb^{2+}$ at a concentration of $0.10 \, M$. Aqueous $HCl$ is added to this solution until the $Cl^{-}$ concentration is $0.10 \, M$. What will the concentrations of $Ag^{+}$ and $Pb^{2+}$ be at equilibrium? ($K_{sp}$ for $AgCl = 1.8 \times 10^{-10}$,$K_{sp}$ for $PbCl_2 = 1.7 \times 10^{-5}$)

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