Which of the following reactions will not give a primary amine?

  • A
    $CH_3CONH_2 \xrightarrow{KOH, Br_2}$
  • B
    $CH_3CN \xrightarrow{LiAlH_4}$
  • C
    $CH_3NC \xrightarrow{LiAlH_4}$
  • D
    $CH_3CONH_2 \xrightarrow{LiAlH_4}$

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Accomplish the following conversions:
$(i)$ Nitrobenzene to benzoic acid
$(ii)$ Benzene to $m-$bromophenol
$(iii)$ Benzoic acid to aniline
$(iv)$ Aniline to $2,4,6-$tribromofluorobenzene
$(v)$ Benzyl chloride to $2-$phenylethanamine
$(vi)$ Chlorobenzene to $p-$chloroaniline
$(vii)$ Aniline to $p-$bromoaniline
$(viii)$ Benzamide to toluene
$(ix)$ Aniline to benzyl alcohol.

In a reaction of aniline,a coloured product $C$ was obtained as shown below:
$A$ $\xrightarrow{NaNO_2/HCl} B$ $\xrightarrow{N,N-dimethylaniline, \text{cold}} C$
The structure of $C$ would be:

Predict the major product $G$ of the following reaction sequence starting from $p$-nitrotoluene.

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Identify the incorrect statements.

The most reactive amine towards dilute hydrochloric acid is ..........

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