Which of the following represents the integrated rate law equation for the gas-phase first-order reaction,$A_{(g)} \rightarrow B_{(g)} + C_{(g)}$? If $P_{i}$ is the initial pressure of $A$ and $P$ is the total pressure of the reaction mixture at time $t$.

  • A
    $k = 2.303 \times \log_{10} \frac{P_{i}}{2P_{i} - P}$
  • B
    $k = \frac{2.303}{t} \times \log_{10} \frac{P_{i}}{2P_{i} - P}$
  • C
    $k = \frac{1}{t} \ln \frac{2P_{i} - P}{P_{i}}$
  • D
    $k = \frac{2.303}{t} \times \log_{10} \frac{P_{i} - P}{P_{i}}$

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