Which of the following statements is correct regarding the $emf$ of the cell for the cell reaction,$Cd_{(s)} + Cu^{2+}_{(aq)} \longrightarrow Cd^{2+}_{(aq)} + Cu_{(s)}$,if the concentration of $Cd^{2+}$ is $10$ times greater than the concentration of $Cu^{2+}_{(aq)}$ at $298 \ K$?

  • A
    greater than $E^{\circ}_{cell}$ by $0.0592 \ V$
  • B
    less than $E^{\circ}_{cell}$ by $0.0592 \ V$
  • C
    greater than $E^{\circ}_{cell}$ by $0.0296 \ V$
  • D
    less than $E^{\circ}_{cell}$ by $0.0296 \ V$

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Similar Questions

If the standard electrode potential of $Cu^{2+}/Cu$ electrode is $0.34 \, V$,what is the electrode potential of $0.01 \, M$ concentration of $Cu^{2+}$ $(T = 298 \, K)$ (in $, V$)?

What will be the $EMF$ for the given cell?
$Pt | H_2(g, P_1) | H^{+}(aq.) (1 \ M) || H^{+}(aq.) (1 \ M) | H_2(g, P_2) | Pt$

Calculate the equilibrium constant of the reaction,$Cu_{(s)} + 2 Ag^{+}_{(aq)} \longrightarrow Cu^{2+}_{(aq)} + 2 Ag_{(s)}$,given that for the reaction $E^{\circ}_{cell} = 0.46 \ V$.

Consider the cell at $25^{\circ} C$:
$Zn | Zn^{2+}_{(aq)} (1 \ M) || Fe^{3+}_{(aq)}, Fe^{2+}_{(aq)} | Pt_{(s)}$
The fraction of total iron present as $Fe^{3+}$ ion at the cell potential of $1.500 \ V$ is $X \times 10^{-2}$. The value of $X$ is $.....$ (Nearest integer).
(Given $E^{0}_{Fe^{3+} / Fe^{2+}} = 0.77 \ V, E^{0}_{Zn^{2+} / Zn} = -0.76 \ V$)

The $EMF$ of the cell $M | M^{n+} (0.02 \, M) || H^{+} (1 \, M) | H_{2(g)} (1 \, atm), Pt$ at $25 \, ^\circ C$ is $0.81 \, V$. Calculate the valency of the metal $(n)$ if the standard oxidation potential of the metal is $0.76 \, V$. (Use $\frac{2.303 \, RT}{F} = 0.06, \log \, 2 = 0.3$)

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