Which of the following statements regarding a chemical equilibrium is wrong?

  • A
    An equilibrium can be shifted by altering the temperature or pressure
  • B
    An equilibrium is dynamic
  • C
    The same state of equilibrium is reached whether one starts with the reactants or the products
  • D
    The forward reaction is favoured by the addition of a catalyst

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Nitric oxide reacts with $Br_{2}$ and gives nitrosyl bromide as per the reaction given below:
$2 NO_{(g)} + Br_{2(g)} \longleftrightarrow 2 NOBr_{(g)}$
When $0.087 \ mol$ of $NO$ and $0.0437 \ mol$ of $Br_{2}$ are mixed in a closed container at constant temperature,$0.0518 \ mol$ of $NOBr$ is obtained at equilibrium. Calculate the equilibrium amount of $NO$ and $Br_{2}$.

$13.8 \,g$ of $N_{2}O_{4}$ was placed in a $1 \,L$ reaction vessel at $400 \,K$ and allowed to attain equilibrium.
$N_{2}O_{4(g)} \rightleftharpoons 2NO_{2(g)}$
The total pressure at equilibrium was found to be $9.15 \,bar$. Calculate $K_{c}$,$K_{p}$,and the partial pressures at equilibrium.

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Solid $NH_4HS$ is placed in a flask containing $NH_3$ gas at a certain temperature and a pressure of $0.50 \ atm$. The $NH_4HS$ decomposes to form $NH_3$ gas and $H_2S$ gas. When equilibrium is established in the flask,the total pressure increases to $0.84 \ atm$. What is the equilibrium constant $(K_p)$ for the decomposition of $NH_4HS$ at this temperature?

$5 \ \text{moles}$ of $SO_2$ and $5 \ \text{moles}$ of $O_2$ are allowed to react to form $SO_3$ in a closed vessel. At the equilibrium stage,$60\%$ of $SO_2$ is used up. The total number of moles of $SO_2$,$O_2$,and $SO_3$ in the vessel now is:

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In a vessel of volume $1 \, dm^3$,$1 \, mol$ of $N_2$ and $2 \, mol$ of $H_2$ are taken for the reaction. If $0.8 \, mol$ of $NH_3$ is obtained at equilibrium,the concentration of $H_2$ in the vessel will be .......... $mol \, dm^{-3}$.

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