Why are $Mn^{2+}$ compounds more stable than $Fe^{2+}$ towards oxidation to their $+3$ state?

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(A) The electronic configuration of $Mn^{2+}$ is $[Ar] \, 3d^{5}$.
The electronic configuration of $Fe^{2+}$ is $[Ar] \, 3d^{6}$.
Half-filled and fully-filled orbitals are more stable due to exchange energy and symmetry. $Mn^{2+}$ has a stable half-filled $d^{5}$ configuration,making it resistant to oxidation to $Mn^{3+}$.
Conversely,$Fe^{2+}$ has a $3d^{6}$ configuration. By losing one electron,it achieves the stable half-filled $3d^{5}$ configuration. Therefore,$Fe^{2+}$ is easily oxidized to the $Fe^{3+}$ state.

Explore More

Similar Questions

What are the different possible oxidation states exhibited by scandium $(Sc)$?

Number of unpaired electrons in $Mn^{4+}$ is

In chromyl chloride,the number of $d$-electrons present on chromium is same as in (Given atomic number of $Ti = 22, V = 23, Cr = 24, Mn = 25, Fe = 26$)

What are $d$-block elements and transition elements? Explain characteristics of $d$-block elements.

Difficult
View Solution

Assertion : Transition metals show variable valency.
Reason : Transition metals have a large energy difference between the $ns^2$ and $(n-1)d$ electrons.

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo