Write a note on the halogen compounds containing $sp^{3} C - X$ bonds with examples.
(N/A) Halogen compounds containing $sp^{3} C - X$ bonds are those in which the halogen atom is bonded to an $sp^{3}$-hybridised carbon atom. These include:
$1$. Alkyl halides $(R-X)$: The halogen atom is bonded to an alkyl group. Examples include $CH_3-CH_2-X$ (Ethyl halide).
$2$. Allylic halides: The halogen atom is bonded to an $sp^{3}$-hybridised carbon atom next to a carbon-carbon double bond $(C=C)$. Example: $CH_2=CH-CH_2-X$.
$3$. Benzylic halides: The halogen atom is bonded to an $sp^{3}$-hybridised carbon atom attached to an aromatic ring. Example: $C_6H_5-CH_2-X$.
$1$. Alkyl halides $(R-X)$: The halogen atom is bonded to an alkyl group. Examples include $CH_3-CH_2-X$ (Ethyl halide).
$2$. Allylic halides: The halogen atom is bonded to an $sp^{3}$-hybridised carbon atom next to a carbon-carbon double bond $(C=C)$. Example: $CH_2=CH-CH_2-X$.
$3$. Benzylic halides: The halogen atom is bonded to an $sp^{3}$-hybridised carbon atom attached to an aromatic ring. Example: $C_6H_5-CH_2-X$.
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Match the type of halide given in Column-$(I)$ with the structures in Column-$(II)$.
Column-$(I)$ (Structure) Column-$(II)$ (Type) $(A)$ $C_6H_5CH_2X$ $(i)$ $4^{\circ}$ Benzylic halide $(B)$ $C_6H_5CH(CH_3)X$ $(ii)$ $3^{\circ}$ Benzylic halide $(C)$ $C_6H_5C(CH_3)_2X$ $(iii)$ $2^{\circ}$ Benzylic halide $(D)$ $C_6H_5X$ $(iv)$ $1^{\circ}$ Benzylic halide $(v)$ Aryl halide
| Column-$(I)$ (Structure) | Column-$(II)$ (Type) |
|---|---|
| $(A)$ $C_6H_5CH_2X$ | $(i)$ $4^{\circ}$ Benzylic halide |
| $(B)$ $C_6H_5CH(CH_3)X$ | $(ii)$ $3^{\circ}$ Benzylic halide |
| $(C)$ $C_6H_5C(CH_3)_2X$ | $(iii)$ $2^{\circ}$ Benzylic halide |
| $(D)$ $C_6H_5X$ | $(iv)$ $1^{\circ}$ Benzylic halide |
| $(v)$ Aryl halide |
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View SolutionIdentify the type of halide given in Column-$I$ from Column-$II$. Column-$I$ Column-$II$ $A$. $CH_2=CHCH_2X$ $i$. Aryl halide $B$. $CH_2=CHX$ $ii$. Benzylic halide $C$. $C_6H_5CH_2X$ $iii$. Allylic halide $D$. $C_6H_5X$ $iv$. Vinylic halide
| Column-$I$ | Column-$II$ |
| $A$. $CH_2=CHCH_2X$ | $i$. Aryl halide |
| $B$. $CH_2=CHX$ | $ii$. Benzylic halide |
| $C$. $C_6H_5CH_2X$ | $iii$. Allylic halide |
| $D$. $C_6H_5X$ | $iv$. Vinylic halide |
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