In the reaction $CH_3COOH + C_2H_5OH \rightleftharpoons CH_3COOC_2H_5 + H_2O$,one mole of each of acetic acid and ethanol is heated in the presence of a little concentrated $H_2SO_4$. When equilibrium is reached,which of the following is true?

For the reaction $N_2 + 3H_2 \rightleftharpoons 2NH_3$,what is the relationship between $\Delta H$ and $\Delta E$?

For a reaction,$A \rightleftharpoons P$,the plots of $[A]$ and $[P]$ with time at temperatures $T_1$ and $T_2$ are given below. If $T_2 > T_1$,the correct statement$(s)$ is (are) (Assume $\Delta H^{\ominus}$ and $\Delta S^{\ominus}$ are independent of temperature and ratio of $\ln K$ at $T_1$ to $\ln K$ at $T_2$ is greater than $T_2 / T_1$. Here $H, S, G$ and $K$ are enthalpy,entropy,Gibbs energy and equilibrium constant,respectively.)
$(A)$ $\Delta H^{\ominus} < 0, \Delta S^{\ominus} < 0$
$(B)$ $\Delta G^{\ominus} < 0, \Delta H^{\ominus} > 0$
$(C)$ $\Delta G^{\ominus} < 0, \Delta S^{\ominus} < 0$
$(D)$ $\Delta G^{\ominus} < 0, \Delta S^{\ominus} > 0$

$0.5 \ mol$ of $CaCO_3(s)$ is heated in a $500 \ mL$ closed vessel at $400 \ K$. The reaction is $CaCO_{3(s)} \rightleftharpoons CaO(s) + CO_{2(g)}$. If the equilibrium constant $K_c = 0.9 \ mol \ L^{-1}$,calculate the amount of $CO_2$ in $mol$ at equilibrium and the percentage of the reaction completed.

For the reaction $PCl_{5(g)} \rightleftharpoons PCl_{3(g)} + Cl_{2(g)}$,the value of $K_c$ is $0.04$ at $250 \ ^oC$ in a $3 \ L$ vessel. If the concentration of $Cl_2$ at equilibrium is $0.15 \ M$,then the initial moles of $PCl_5$ will be ...........

$28 \, g$ of $N_2$ and $6 \, g$ of $H_2$ were kept at $400 \, ^oC$ in a $1 \, L$ vessel. The equilibrium mixture contained $27.54 \, g$ of $NH_3$. The approximate value of $K_c$ for the reaction $N_2(g) + 3H_2(g) \rightleftharpoons 2NH_3(g)$ is (in $L^2 \, mol^{-2}$):