When a person breathes rapidly during fear or excitement,the concentration of $CO_2$ in the blood decreases. What happens to the $pH$ of the blood?

One litre buffer solution was prepared by adding $0.10 \ mol$ each of $NH_3$ and $NH_4Cl$ in deionised water. The change in $pH$ on addition of $0.05 \ mol$ of $HCl$ to the above solution is $............ \times 10^{-2}$ ($Nearest$ $integer$) ($Given$: $pK_b$ of $NH_3 = 4.745$ and $\log_{10} 3 = 0.477$)

The $pH$ of a buffer solution obtained by mixing $50 \ mL$ of $0.1 \ M$ $NH_4OH$ and $25 \ mL$ of $2.0 \ M$ $NH_4Cl$ is ($pK_b$ of $NH_4OH$ is $4.8$).

$A$ buffer solution can be prepared from a mixture of

Find the value of $\frac{[NaCN]}{[HCN]}$ given the $pH$ of the buffer solution of $NaCN$ and $HCN$ is $9.3$ and $K_a$ of $HCN$ is $5 \times 10^{-10}$.

Calculate the molar ratio of a weak acid $HA$ $(K_a=10^{-6})$ and its salt with a strong base,so that the $pH$ of the buffer solution is $6$.