In the reaction $H_2 + Cl_2 \rightarrow 2HCl$,heat is released. The bond energies of $H-H$ and $Cl-Cl$ are $430 \ kJ \ mol^{-1}$ and $242 \ kJ \ mol^{-1}$ respectively. If the enthalpy of reaction is $-182 \ kJ \ mol^{-1}$,the bond energy of $H-Cl$ is . . . . . . $kJ \ mol^{-1}$.

The heat of combustion of solid benzoic acid at constant volume is $-321.30 \ kJ$ at $27^{\circ} C$. Its heat of combustion at constant pressure is :

Three thermochemical equations are given below:
$(i) C_{(graphite)} + O_{2(g)} \to CO_{2(g)}; \Delta_r H^\circ = x \ kJ \ mol^{-1}$
$(ii) C_{(graphite)} + \frac{1}{2} O_{2(g)} \to CO_{(g)}; \Delta_r H^\circ = y \ kJ \ mol^{-1}$
$(iii) CO_{(g)} + \frac{1}{2} O_{2(g)} \to CO_{2(g)}; \Delta_r H^\circ = z \ kJ \ mol^{-1}$
Based on the above equations,find out which of the relationship given below is correct.

If the heat of formation of $CO_2$ is $-393 \ kJ/mol$,the amount of heat evolved in the formation of $0.156 \ kg$ of $CO_2$ is.....$kJ$.

The following thermochemical reactions are given:
$M + \frac{1}{2} O_2 \to MO + 351.4 \ kJ$ $(i)$
$X + \frac{1}{2} O_2 \to XO + 90.8 \ kJ$ $(ii)$
It follows that the heat of reaction for the following process $M + XO \rightleftharpoons MO + X$ is given by $... \ kJ$.

For strong acid and strong base neutralisation,the net chemical change is $H^{+} + OH^{-} \longrightarrow H_2O_{(l)}$; $\Delta_r H^{\circ} = -55.84 \ kJ \ mol^{-1}$. If the enthalpy of neutralisation of $CH_3COOH$ by $NaOH$ is $-49.86 \ kJ \ mol^{-1}$,then the enthalpy of ionisation of $CH_3COOH$ is: