For an octahedral complex of $Co$ $(Z = 27)$,which of the following has the highest value of $\Delta_0$?

  • A
    $[Co(CN)_6]^{3-}$
  • B
    $[Co(C_2O_4)_3]^{3-}$
  • C
    $[Co(H_2O)_6]^{3+}$
  • D
    $[Co(NH_3)_6]^{3+}$

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The correct order for wavelengths of absorption in the visible region for the following complexes will be

Match the electronic configurations in List-$I$ with appropriate metal complex ions in List-$II$ and choose the correct option.
[Atomic Number: $Fe=26, Mn=25, Co=27$]
List-$I$ List-$II$
$P$. $t_{2g}^6 e_g^0$ $1$. $[Fe(H_2O)_6]^{2+}$
$Q$. $t_{2g}^3 e_g^2$ $2$. $[Mn(H_2O)_6]^{2+}$
$R$. $e^2 t_2^3$ $3$. $[Co(NH_3)_6]^{3+}$
$S$. $t_{2g}^4 e_g^2$ $4$. $[FeCl_4]^{-}$
$5$. $[CoCl_4]^{2-}$

The order of absorption wavelength in the visible region for the following complexes is:

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Given below are two statements:
Statement $I$: Among $Zn$, $Mn$, $Sc$ and $Cu$, the energy required to remove the third valence electron is highest for $Zn$ and lowest for $Sc$.
Statement $II$: The correct order of the following complexes in terms of $CFSE$ is $[Co(H_2O)_6]^{2+} < [Co(H_2O)_6]^{3+} < [Co(en)_3]^{3+}$.

The complex ion that will lose its crystal field stabilization energy upon oxidation of its metal to $+3$ state is

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