The pH of a solution obtained by mixing $5 \text{ mL}$ of $0.1 \text{ M } NH_4OH$ solution with $250 \text{ mL}$ of $0.1 \text{ M } NH_4Cl$ solution is . . . . . . $\times 10^{-2}$.

Which of the following solutions cannot act as a buffer?

$50 \, mL$ of $0.1 \, M \, CH_3COOH$ is being titrated against $0.1 \, M \, NaOH$. When $25 \, mL$ of $NaOH$ has been added,the $pH$ of the solution will be $.... \times 10^{-2}$. (Nearest integer)
(Given : $pK_a(CH_3COOH) = 4.76$)
$\log 2 = 0.30$,$\log 3 = 0.48$,$\log 5 = 0.69$,$\log 7 = 0.84$,$\log 11 = 1.04$

$A$ certain buffer solution contains equal concentrations of $X^-$ and $HX$. If the $K_a$ of $HX$ is $10^{-8}$,then the $pH$ of the buffer solution will be ...... .

Give the importance of buffer solution.

Which of the following solutions does not act as a buffer $:-$