The rate constant of a chemical reaction at a very high temperature will approach:

  • A
    Arrhenius frequency factor divided by the ideal gas constant
  • B
    Activation energy
  • C
    Arrhenius frequency factor
  • D
    Activation energy divided by the ideal gas constant

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$A$ reaction takes place in three steps with individual rate constants and activation energies. The overall rate constant is given by $k = (\frac{k_1 k_2}{k_3})^{2/3}$. The overall activation energy of the reaction in $kJ/mol$ is:
$Step$ $Rate\ Constant\ /\ Activation\ energy$
$Step\ 1$ $k_1, E_{a_1} = 180\ kJ/mol$
$Step\ 2$ $k_2, E_{a_2} = 80\ kJ/mol$
$Step\ 3$ $k_3, E_{a_3} = 50\ kJ/mol$

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The specific rate constant of a $1^{st}$ order reaction depends on the

Define the following terms:
$1.$ Collision
$2.$ Frequency of collision

Catalyst $A$ reduces the activation energy for a reaction by $10 \ kJ \ mol^{-1}$ at $300 \ K$. The ratio of rate $\frac{k_{T, \text{Catalysed}}}{k_{T, \text{Uncatalysed}}}$ is $e^{x}$. Find the value of $x$ [nearest integer].
[Assume that the pre-exponential factor is same in both the cases.
Given $R = 8.31 \ J \ K^{-1} \ mol^{-1}$]

The activation energy of a reaction at a given temperature is found to be $2.303 \ RT \ J \ mol^{-1}$. The ratio of rate constant to the Arrhenius factor is

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