The van't Hoff factor $i$ for a compound which undergoes dissociation in one solvent and association in another solvent is respectively:

  • A
    less than $1$ and greater than $1$
  • B
    less than $1$ and less than $1$
  • C
    greater than $1$ and less than $1$
  • D
    greater than $1$ and greater than $1$

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$2\,g$ of benzoic acid $(C_6H_5COOH)$ dissolved in $25\,g$ of benzene shows a depression in freezing point equal to $1.62\,K$. The molal depression constant $(K_f)$ for benzene is $4.9\,K\,kg\,mol^{-1}$. What is the percentage degree of association of the acid?

What is association? What is dissociation?

$2$ molal solution of a weak acid $HA$ has a freezing point of $-3.885^{\circ} C$. The degree of dissociation of this acid is ........ $\times 10^{-3}$. (Round off to the Nearest Integer).
[Given: Molal depression constant of water = $1.85 \ K \ kg \ mol^{-1}$,Freezing point of pure water = $0^{\circ} C$]

The freezing point of a $0.262 \ mol \ kg^{-1}$ solution of acetic acid in benzene is $277.4 \ K$. If the $K_f$ value for benzene is $5.0 \ K \ kg \ mol^{-1}$ and the freezing point of pure benzene is $278.4 \ K$,then the van't Hoff factor is ...........

Determination of the molar mass of acetic acid in benzene using freezing point depression is affected by

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