Which of the following statements or relationships is not correct in thermodynamic changes?

  • A
    $\Delta U = 0$ (isothermal reversible expansion of a gas)
  • B
    $w = - nRT \ln \frac{V_2}{V_1}$ (isothermal reversible expansion of an ideal gas)
  • C
    $w = nRT \ln \frac{V_2}{V_1}$ (isothermal reversible expansion of an ideal gas)
  • D
    For a system of constant volume,heat involved directly changes to internal energy.

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Assertion $(A)$: If heat of combustion of $C_2H_6$ is $X \ kJ \ mol^{-1}$,heat liberated on combustion of $150 \ g$ of $C_2H_6$ is $5X \ kJ$.
Reason $(R)$: Enthalpy is an extensive property.

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List-$I$List-$II$
$(A) \Delta U = W_{ad}$$I.$ Isothermal reversible expansion
$(B) \Delta U = q - W$$II.$ Wall is adiabatic
$(C) \Delta U = -q$$III.$ Thermally conducting walls
$(D) \Delta U = 0$$IV.$ Isolated system
$V.$ Closed system

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What is the enthalpy of vaporization of ethanol in $kJ/mol$? Given: boiling point $(b.p.)$ = $79.5 \, ^\circ C$ and entropy change $(\Delta S_{vap})$ = $109.8 \, J K^{-1} mol^{-1}$.

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