$0.1 \ M, 60 \ mL$ $NH_4Cl$ $(K_h = 10^{-9})$ is titrated against $0.2 \ M$ $NaOH$. What is the $pH$ at the $\frac{1}{3}$ equivalence point?

$pH$ of a mixture of $1 \ M \ HA$ $(pK_a = 4.2)$ and $1 \ M \ NaA$ is $4.5$. In $300 \ mL$ of buffer,the volume of $HA$ is $....... \ mL$ $[\log \ 2 = 0.3]$

When a person breathes rapidly during fear or excitement,the concentration of $CO_2$ in the blood decreases. What happens to the $pH$ of the blood?

To prepare a buffer solution of $pH = 6$ by mixing sodium acetate and acetic acid,what should be the ratio of the concentration of salt to acid? $(K_a = 10^{-5})$

$100 \ mL$ of a solution contains $0.1 \ M$ $NH_4OH$ and $0.1 \ M$ $NH_4Cl$. The $pH$ of the solution will not change on adding :-

$A$ buffer solution contains $0.1 \ mol$ of sodium acetate dissolved in $1000 \ cm^{3}$ of $0.1 \ M$ acetic acid. To the above buffer solution,$0.1 \ mol$ of sodium acetate is further added and dissolved. The $pH$ of the resulting buffer is