The bond energy is the energy required to

The heat of neutralization of which acid and base is close to $-13.6 \ kcal/mol$?

Given: $2Zn + O_2 \rightarrow 2ZnO, \Delta G^o = -616 \, J$; $2Zn + S_2 \rightarrow 2ZnS, \Delta G^o = -293 \, J$; $S_2 + 2O_2 \rightarrow 2SO_2, \Delta G^o = -408 \, J$. The value of $\Delta G^o$ for the reaction $2ZnS + 3O_2 \rightarrow 2ZnO + 2SO_2$ is ....... $J$.

Diborane is formed from the elements as shown in equation $(i)$:
$2 B_{(s)} + 3 H_{2(g)} \longrightarrow B_2H_{6(g)} \dots (i)$
Given that:
$H_2O_{(l)} \longrightarrow H_2O_{(g)}, \quad \Delta H_1^{\circ} = 44 \, kJ$
$2 B_{(s)} + \frac{3}{2} O_{2(g)} \longrightarrow B_2O_{3(s)}, \quad \Delta H_2^{\circ} = -1273 \, kJ$
$B_2H_{6(g)} + 3 O_{2(g)} \longrightarrow B_2O_{3(s)} + 3 H_2O_{(g)}, \quad \Delta H_3^{\circ} = -2035 \, kJ$
$H_{2(g)} + \frac{1}{2} O_{2(g)} \longrightarrow H_2O_{(l)}, \quad \Delta H_4^{\circ} = -286 \, kJ$
The $\Delta H^{\circ}$ for the reaction $(i)$ is $..... \, kJ$.

Which of the following reactions is not exothermic?

The standard enthalpy of formation of $NH_3$ is $-46.0 \ kJ \ mol^{-1}.$ If the enthalpy of formation of $H_2$ from its atoms is $-436 \ kJ \ mol^{-1}$ and that of $N_2$ is $-712 \ kJ \ mol^{-1},$ the average bond enthalpy of $N-H$ bond in $NH_3$ is ................ $kJ \ mol^{-1}$