The most stable complex among the following is

  • A
    ${K_3}[Al(C_2O_4)_3]$
  • B
    $[Pt(en)_2]Cl_2$
  • C
    $[Ag(NH_3)_2]Cl$
  • D
    ${K_2}[Ni(EDTA)]$

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The complex formed during the brown ring test of nitrate $(NO_3^-)$ ion is:

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Which of the following is a spin-free complex?

Which of the following complexes has the highest $C-O$ bond length?

From the stability constant (hypothetical values) given below,predict which is the strongest ligand:

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The stepwise formation of $[Cu(NH_{3})_{4}]^{2+}$ is given below:
$Cu^{2+} + NH_{3} \rightleftharpoons [Cu(NH_{3})]^{2+} \quad K_{1}$
$[Cu(NH_{3})]^{2+} + NH_{3} \rightleftharpoons [Cu(NH_{3})_{2}]^{2+} \quad K_{2}$
$[Cu(NH_{3})_{2}]^{2+} + NH_{3} \rightleftharpoons [Cu(NH_{3})_{3}]^{2+} \quad K_{3}$
$[Cu(NH_{3})_{3}]^{2+} + NH_{3} \rightleftharpoons [Cu(NH_{3})_{4}]^{2+} \quad K_{4}$
The values of stability constants $K_{1}, K_{2}, K_{3}$ and $K_{4}$ are $10^{4}, 1.58 \times 10^{3}, 5 \times 10^{2}$ and $10^{2}$ respectively. The overall equilibrium constant for dissociation of $[Cu(NH_{3})_{4}]^{2+}$ is $x \times 10^{-12}$. The value of $x$ is ...............
(Rounded off to the nearest integer)

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