The heat evolved during the combination of $24 \, g$ of $C$ and $128 \, g$ of $S$ according to the reaction $C + 2S \to CS_2$ with $\Delta H = 22.0 \, kcal$ is:

The molar enthalpy change for $H_2O_{(l)} \rightleftharpoons H_2O_{(g)}$ at $373 \ K$ and $1 \ atm$ is $41 \ kJ \ mol^{-1}$. Assuming ideal behavior,the internal energy change for vaporization of $1 \ mol$ of water at $373 \ K$ and $1 \ atm$ in $kJ \ mol^{-1}$ is:

The ${\Delta _c}{U^\circ}$ of combustion of $CH_{4(g)}$ at a certain temperature is $-100 \ kJ/mol$. The value of ${\Delta _c}{H^\circ}$ is

Given below are two statements:
Statement $I$: For an ideal gas, heat capacity at constant volume is always greater than the heat capacity at constant pressure.
Statement $II$: In a constant volume process, no work is produced and all the heat withdrawn goes into the chaotic motion and is reflected by a temperature increase of the ideal gas.

$10 \ g$ each of $NH_3, N_2, Cl_2$ and $H_2S$ are expanded isothermally and reversibly at the same temperature. Identify the gas that performs maximum work.

The $\Delta E^o$ of combustion of $2-$methylpropene is $-X \ kJ \ mol^{-1}$. The value of $\Delta H^o$ is